Phosphorus Oxychloride is generally immediately available in most volumes, including bulk orders. Will not burn under typical fire conditions. This produces heat and decomposition products including hydrochloric acid and phosphoric acid. Manufacturing of pharmaceutical agents. USA.gov. DOT ID & Guide. Your institution may already be a subscriber. Acts a source of liquid phosphorus … This section provides a listing of alternate names for this chemical, Do not store with combustible materials, particularly fibrous organic materials, or with electrical or other equipment that can be corroded. All chemicals have Substance information for UN 1810 - Phosphorous oxychloride based on the Hazardous Materials Table (Title 49 CFR 172.101) to assist in preparing a risk assessment for loading, transporting and storing hazardous materials. Freeman, and W.D. breakthrough time; permeation rates typically increase with NACRES NA.22 ... in connection with this information. Readily undergoes violent chemical changes at elevated temperatures and pressures. This produces toxic and corrosive fumes including hydrogen chloride and phosphorus oxides. this information. Avoid breathing vapors; keep upwind. Phosphorus(V) oxychloride is widely used as a dehydrating agent and a chlorinating agent. these chemicals are present. Fumes in air. POCl3 Molar weight. Normalized breakthrough times seams and closures have shorter breakthrough times and higher permeation PHOSPHORUS OXYCHLORIDE PPO CAUTIONARY RESPONSE INFORMATION Common Synonyms Oily liquid Colorless to light yellow Musty odor Fumes in air, sinks and reacts with water. on behalf of the United States of America. Reacts violently with water. Very toxic by inhalation and corrosive to metals and tissue. TH4897000. Phosphoryl chloride can be prepared by the reaction of phosphorus trichloride with oxygenat 20-50 °C (air is ineffective): 2 PCl3 + O2 → 2 O=PCl3 An alternative synthesis involves the reaction of phosphorus pentachloride and phosphorus pentoxide. EC Number 233-046-7. Get Contact details & address of companies manufacturing and supplying Phosphorus Oxychloride… reported in minutes. Phosphorus(V) oxychloride 99.999% Synonym: Phosphorus(V) oxide chloride, Phosphoryl chloride CAS Number 10025-87-3. Phosphorus Oxychloride (also called Phosphoryl Chloride) 10025-87-3: 1000 pounds: Phosphoryl Chloride (also called Phosphorus Oxychloride) 10025-87-3: 1000 pounds shall not be liable for any damage that may result from It causes burns of the mucous membranes of the mouth and digestive tractand may be fatal. from the permeation behavior of the individual chemicals. uses its best efforts to deliver a high quality copy of the A colorless fuming liquid with a pungent odor. If contact with the material is anticipated, wear full protective clothing. Warning: Phosphorus oxychloride is a corrosive agent. Reacts violently with alcohols, phenols, amines and many other materials. Phosphorus oxychloride. If fabric Its EINECS registry number is 233-046-7. (EPA, 1998), PHOSPHORUS OXYCHLORIDE is water reactive. It hydrolyses in moist air releasing phosphoric acid and fumes of hydrogen chloride. rates than the fabric. Application P 1755 (OTTO) Phosphorous oxychloride, 98% Cas 10025-87-3 - used in the manufacture of phosphate esters. A different temperature may have significant influence on the It reacts violently with water. (method A and B) or ASTM D6978 test methods. Since conditions of use American Elements can produce materials to custom specifications by request, in addition to custom compositions for commercial and research applications and new proprietary technologies. In many cases, 10025-87-3) Skype Phosphorus Oxychloride (CAS No. The Phosphorus oxychloride with CAS registry number of 10025-87-3 is also known as Trichlorophosphine oxide. 8, 1025]. under or a recommendation to infringe any patent or technical information COMPATIBILITY CHEMICAL COMPATIBILITY Chemicial Compatibility Guide The following information is intended to be used as a general guideline for pump material selection. Useful for the conversion of amide to nitriles, Bischler-Napieralski reaction, Vilsmeier Haak reaction, and other reactions producing commercially important intermediates. that the garment selected is suitable for the intended use. Get contact details & address of companies manufacturing and supplying Phosphorus Oxychloride… Data Program, but require an annual fee to access. Skin: Wear appropriate personal protective clothing to prevent skin contact. Keep people away. What is Idelalisib? It is the first oral and selective phosphoinositol 3-kinase delta(PI3K-delta, P110-delta) inhibitor. National Oceanic and Atmospheric Administration. Do not handle broken packages without protective equipment. The systematic name is Phosphoric trichloride. Linear Formula POCl 3. Use caution: Liquids with this reactive group classification have been and risk. Experimental details are in the following: "Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response Guidebook", ANL/DIS-09-2, D.F. Combining the chloride with zinc dust caused immediate ignition, due to the formation of phosphine gas which ignites, [Mellor, 1940, Vol. Database and to verify that the data contained therein have Phosphoryl chloride (commonly called phosphorus oxychloride) is a colourless liquid with the formula POCl3. Freezing point is 34°F. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Phosphorus oxychloride reacts vigorously with water to generate gaseous HCl. including trade names and synonyms. Agriculture. Incompatible with strong oxidizing agents, alcohols, bases (including amines). 6,200, "Phosphorus Oxychloride and Acetone: An Incompatibility Investigation Using ARC. www.sciencemadness.org/smwiki/index.php/Phosphoryl_chloride Suppliers List, E-mail/RFQ Form, Molecular Structure, Weight, Formula, IUPAC, Synonyms for Phosphorus Oxychloride (CAS No. (EPA, 1998), Health Hazards : This poison is toxic by inhalation and ingestion and is strongly irritating to skin and tissues. CAS Number: 10025-87-3 Molecular formula POCl3, molecular weight 153.33. Synonyms & Trade Names Phosphorus chloride [Phosphorus oxychloride], Phosphorus oxytrichloride, Phosphoryl chloride CAS No. errors or omissions in the Database. Haney, Argonne National Laboratory, Argonne, Illinois, June 2009. National Institute of Standards and Wear self-contained breathing apparatus. : 015-009-00-5 REACH No. Caution is advised. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur Phosphoryl chloride Evacuate. It is manufactured … The fabric permeation data was generated for DuPont by independent * Phosphorus Oxychloride is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. Reacts exothermically (with possible spattering) with water to form fumes of phosphoric acid and hydrochloric acid. performance of fabrics, not complete garments, under controlled conditions. In addition, the formula is Cl 3 OP and the molecular weight is 155.33. of DuPont or others covering any material or its use. Serged and bound seams are degraded by some hazardous liquid Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) known to react with the PHOSPHORYL CHLORIDE {PHOSPHORUS OXYCHLORIDE}. 27°C unless otherwise stated. 153.4. Standard Reference Data Act. It is mainly used to make phosphate esters such as tricresyl phosphate. stated. Related Pages. If an oxygen atom is simply replaced by a halogen atom the charge increases by +1, but the coordination number is unchanged. An exotherm starting with the mixing of phosphorus oxychloride with acetone (a ketone) lead to an explosion, may behave similarly with other ketones, [Organic Process Research and Development, Vol.4, No. Wash away any material which may have contacted the body with copious amounts of water or soap and water. As the PCl3 is consumed, the POCl3becomes the reaction solvent. Anyone intending to use this information should first verify determine the level of toxicity and the proper personal protective chemicals, such as strong acids, and should not be worn when MDL number MFCD00011443. equipment needed. Technology, Office of Data More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. Phosphorus oxychloride agent detailed information in Haz-Map database. All rights reserved. attached gloves, visors, etc. Wear boots, protective gloves, and goggles. relative humidity per military standard MIL-STD-282. 9 Phosphorus-oxychloride … Follow the links above to find out more about the data Phosphorus oxychloride; [Phosphoryl chloride], Phosphorus Oxychloride (also called Phosphoryl Chloride), Phosphoryl Chloride (also called Phosphorus Oxychloride). The information set forth herein reflects laboratory Chemical Industry. Since these compounds are both solids, a convenient way of performing the reaction is to chlorinate a mixture of PCl3 and P4O10, which generates the PCl5 in situ. absorbents Copyright for NIST Standard Reference Data is governed by It is intended for informational use by persons having technical skill for "], Belongs to the Following Reactive Group(s). However, NIST makes no warranties to that effect, and NIST Reacts violently with moisture. the Used in gasoline additives and hydraulic fluids. NIST subscription sites provide data under the All liquid chemicals have been tested between approximately 20°C and NR = Not recommended due to insufficient data. been selected on the basis of sound scientific judgment. are outside our control, we make no warranties, express or implied, Avoid bodily contact with the material. Benzo Chem Corporation - Offering PHOSPHORUS OXYCHLORIDE, POCl3, 10025-87-3, Phosphoric chloride, Phosphoric trichloride, Phosphorus chloride oxide, Dilute Phosphorus Oxychloride in Masjid Bandar, Mumbai, Maharashtra. Web site owner: been tested at a concentration of greater than 95% unless otherwise Office of Response and Restoration, becomes torn, abraded or punctured, or if seams or closures fail, or if Get contact details and address| ID: 22285708697 and Informatics, Vibrational and/or electronic energy levels, Computational Chemistry Comparison and Benchmark Database, X-ray Photoelectron Spectroscopy Database, version 4.1, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data). It is a colourless liquid with the formula POCl 3. Phosphoryl chloride is an etherification and esterification agent for modification of food starch. Please contact DuPont for specific data. When heated to decomposition, it emits toxic fumes of chlorides and oxides of phosphorus; it will react with water or steam to produce heat and toxic and corrosive fumes. Poisonous, corrosive, and irritating gases are generated when this material is heated or is in contact with water. Brown, H.M. Hartmann, W.A. Phosphorus oxychloride is produced by oxidizing phosphorus trichloride or by reacting phosphorus pentachloride with phosphorus pentoxide. Reacts violently or explosively with water. Molecular Weight 153.33 . CAUTION: This information is based upon technical data that evaluation under their specific end-use conditions, at their own discretion (the time at which the permeation rate is equal to 0.1 µg/cm2/min) CAS (CAS Number) 10025-87-3. Keep unnecessary people away; isolate hazard area and deny entry. Formula POCl3 Density 1.675 g/ml Molecular Weight 153.33 Vapor Density 5.3 (air = 1) Flash Point non‐flammable TLV 0.5 ppm Boiling Point 105°C @ 760mm Hg Freezing Point 1.2°C APPLICATIONS Liquid phosphorus source used for N‐Type diffusion doping This information is not intended as a license to operate additional knowledge and experience are gained. It is used in the manufacture of phosphate esters that are used in plasticizers, hydraulic fluids, pesticides, and flame retardants, and in the manufacture of several pharmaceuticals. Phosphoryl chloride (commonly called phosphorus oxychloride) is a colourless liquid with the formula POCl3. NIST Standard Reference Phosphorus oxychloride Product Information Molecular Formula. Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% Find here Phosphorus Oxychloride, POCl3 manufacturers, suppliers & exporters in India. The purpose of the fee is to recover costs associated Phosphoryl chloride (commonly called phosphorus oxychloride) is a colourless liquid with the formula 3. 10025-87-3) Suppliers Formula. for a particular use and assume no liability in connection with any use of Phosphorus oxychloride | POCl3 or Cl3OP | CID 24813 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. It hydrolyses in moist air to phosphoric acid to release choking fumes of hydrogen chloride. It is manufactured industrially on a large scale from phosphorus trichloride and oxygen or phosphorus pentoxide. temperature. of garment to avoid potential exposure to chemical. For example, both phosphorus oxychloride, POCl 3 and phosphorus pentachloride, PCl 5 are neutral covalent compounds of phosphorus in the +5 oxidation state. It is subject to revision as Formula: Cl 3 OP; Molecular weight: 153.332; IUPAC Standard InChI: 6 PCl3 + 6 Cl2 → 6 PCl5 6 PCl5 + P4O1… Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Acyl Halides, Sulfonyl Halides, and Chloroformates. Phosphorus-oxychloride Manufacturers. Synonym: Phosphorus(V) oxide chloride, Phosphoryl chloride Linear Formula: POCl 3. Formula: POCl 3 are damaged, end user should discontinue use DuPont believes to be reliable. Unless otherwise stated, permeation was measured for single chemicals. DuPont makes no Density 14.0 lb / gal. PubChem Substance ID 24855857. such sites. 10025-87-3 RTECS No. Fertilizers. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Hydrogen Chloride (hydrochloric acid) gas will be created in 0.12 minutes. Avoid contact with … Product Applications Pharmaceutical industry Biotechnology. The permeation characteristics of mixtures can deviate considerably with the development of data collections included in Chemical synthesis. Molecular Formula: Cl3OP: Molecular Weight (g/mol) 153.323: MDL Number: MFCD00011443: InChI Key: XHXFXVLFKHQFAL-UHFFFAOYSA-N: Synonym: phosphorus oxychloride,phosphoryl chloride,phosphoric trichloride,phosphoryl trichloride,phosphoroxychloride,trichlorophosphine oxide,phosphorus oxytrichloride,fosforoxychlorid,phosphorous oxychloride,phosphorylchlorid: PubChem CID listed below. phosphorus oxychloride,phosphoryl chloride,phosphoric trichloride,phosphoryl trichloride,phosphoroxychloride,trichlorophosphine oxide,phosphorus … Common Name: PHOSPHORUS OXYCHLORIDE CAS Number: 10025-87-3 DOT Number: UN 1810 (PIH) ----- HAZARD SUMMARY * Phosphorus Oxychloride can affect you when breathed in and by passing through your skin. including, without limitation, no warranties of merchantability or fitness Companies involved in Phosphorus-oxychloride production, a key sourcing item for solar cell manufacturers. This generates fire and explosion hazard. By participating in the transformation of B lymphocytes’ immune environment, p110-delta plays a vital role in the activation, proliferation, survival, and migration(trafficking)of these tumor cells. Read about company. 1810 137. It hydrolyses in moist air releasing phosphoric acid and fumes of hydrogen chloride. CAS: 10025-87-3 EINECS: 233-046-7 Synonyms: Phosphorus (V) oxide chloride , Phosphorus oxychloride © 2018 by the U.S. Secretary of Commerce National Ocean Service, XHXFXVLFKHQFAL-UHFFFAOYSA-N. Synonym. in these sites and their terms of usage. Product name : Phosphorus(V) oxychloride Product Number : 201170 Brand : Aldrich Index-No. Mat., 1981, 4, 291]. Molecular Weight: 153.33. guarantee of results and assumes no obligation or liability... CW/CWP = chemical weapons/chemical weapons precursors. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 : A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later Find here Phosphorus Oxychloride, POCl3 manufacturers & OEM manufacturers India. Poisonous gas is produced. It is the user's responsibility to Phosphorus oxychloride. Phosphorus oxychloride is also known as phosphoryl chloride, oxygen and phosphorus chloride. It may ignite other combustible materials (wood, paper, oil, etc.). Contact with eyes may result in severe damage to the cornea, conjunctiva, and blood vessels. Incompatible with carbon disulfide; N,N-dimethylformamide; 2,5-dimethylpyrrole; 2,6-dimethyl- pyridine N-oxide; dimethylsulfoxide; Ferrocene-1,1-dicarboxylic acid; water; and zinc.